2 cups (250 grams) all-purpose flour2 cups (440 grams) firmly packed light brown sugar1½ teaspoons (7.5 grams) baking soda¾ teaspoon (2.25 grams) kosher salt⅔ cup (50 grams) Dutch process cocoa powder1 cup (240 grams) hot brewed coffee or hot water (165°F/74°C to 170°F/77°C)⅔ cup (160 grams) sour cream½ cup (112 grams) vegetable oil2 teaspoons (8 grams) vanilla extract2 large eggs (100 grams)Marshmallow Filling (recipe follows)Chocolate Glaze (recipe follows)
Preheat oven to 325°F (170°C).
In a large bowl, whisk together flour, brown sugar, baking soda, and salt.
In a medium bowl, place cocoa; whisk in hot coffee or hot water until smooth and well combined. Whisk in sour cream, oil, and vanilla until well combined. Whisk in eggs until well combined. Whisk cocoa mixture into flour mixture until no dry streaks remain.
Spray a 10-cup Bundt pan with baking spray with flour; using a pastry brush, spread baking spray into nooks of pan. Pour batter into prepared pan.
Bake until a wooden pick inserted near center comes out with a few moist crumbs, 55 minutes to 1 hour. Let cool in pan for 10 minutes. Invert cake onto a wire rack, and let cool completely.
Using a large serrated knife, cut cooled cake in half horizontally. Using a cake lifter or cake board, remove top half of cake, and reserve. Place bottom half on a serving platter.
Place Marshmallow Filling in a pastry bag fitted with a ½-inch round piping tip (Ateco #807). Pipe onto bottom half of cake as desired. Place top half of cake on filling. Spoon Chocolate Glaze onto cake. Best served same day as made. Cover and refrigerate for up to 2 days.