In a small bowl, stir together warm milk, yeast, and 1 teaspoon (4 grams) sugar until well combined. Let stand until foamy, about 10 minutes.
In the bowl of a stand mixer fitted with the paddle attachment, whisk together 2 cups (250 grams) flour, salt, and remaining ½ cup (100 grams) sugar. Add yeast mixture, and beat at low speed until combined. Add 1 egg (50 grams) and vanilla, beating until combined. With mixer on low speed, gradually add remaining cups 1⅔ cups (208 grams) flour, beating just until dough comes together and stopping to scrape sides of bowl.
Switch to the dough hook attachment. With mixer on low speed, add butter, 1 cube at a time, beating until combined after each addition. Beat until dough is elastic and smooth, 8 to 10 minutes.
Spray a large bowl with cooking spray. Place dough in bowl, turning to grease top. Cover and let rise in a warm, draft-free place (75°F/24°C) until doubled in size, 2 to 2½ hours. (Alternatively, cover and refrigerate overnight.)
Line 2 baking sheets with parchment paper.
Lightly punch down dough. Cover and let stand for 10 minutes. Turn out dough onto a very lightly floured surface. Divide dough into 12 portions (about 75 grams each). Using the palm of your hands, gently shape each portion of dough into a smooth ball, lightly flouring your hands as needed. Using the palm of your hand, firmly press down on dough to flatten slightly. Place 3 to 4 inches apart on prepared pans. Cover with lightly greased plastic wrap, and let rise in a warm, draft-free place (75°F/24°C) until doubled in size, 1½ to 2 hours.
Preheat oven to 375°F (190°C).
In another small bowl, whisk together 1 tablespoon (15 grams) water and remaining egg (50 grams) until well combined. Using a pastry brush, brush egg wash on top and sides of dough.
Bake until golden brown and an instant-read thermometer inserted near center registers 190°F (88°C), 8 to 10 minutes. Let cool on pans for 5 minutes. Remove from pans, and let cool completely on wire racks.
Carefully dip top of each cooled bun into Crème Brûlée Glaze. Return to wire racks, and let stand until glaze is set, about 10 minutes.
Carefully poke bottom of each bun with a paring knife. Transfer Maple Cream Filling to a pastry bag fitted with a ¼-inch round piping tip. Pipe filling into buns. Best served same day. Refrigerate in an airtight container for up to 3 days.